The Way of the Warrior is the best season opener of any Star Trek series
It's got it all:
\- DS9 turning into a photon-launching, phaser-firing badass menace (the camera pan across DS( firing out phasers left, right and centre always gives me chills)
\- quality banter between Garak & Dukat
\- introduction of Worf
\- introduction of Martok
\- introduction of a BALD Sisko
\- Gowron and his manson lamps
\- epic 90s Star Trek space battles
\- treaties being broken
\- Quark laying down some wisdom
\- Kira, Dax & Sisko beating down Klingons hand-to-hand
\- first time seeing and hearing the reworked opening credits and title music
It's a pretty significant turn in the feel and arc of DS9 as a whole. It's really where the show comes into it's own for mine. I can't think of a better season opener to any other Star Trek series.
That is all.