Using two different WiFi adapters simultaneously Windows 11

Hey, I've got a particular set up that I need two adapters working at the same time for, I've googled this question, and found many people asking the same question, but no real answers on how.

I have motherboard with inbuilt Wi-Fi. This has been great because it accepts magic packets. So when I am out, I SSH into a Raspberry pi, which runs a snippet sending a magic packet to wake my computer from sleep, then remote desktop to my computer. I have been remoting in to my computer for a while and this setup works for me.

Recently I got a Wi-Fi 6e enabled router, and then installed a PCIe Wi-fi 6e adapter in my computer. I rent an apartment and the setup means I can't use ethernet to get to my office. Having tried powerline adapters a few years ago, they caused nothing but headaches, so that is off the table.

The problem now is that the PCIe Wi-Fi adapter sleeps with the computer.

**So my question is: Can I set Windows 11 up in such a way that both adapters are running, but the PCIe is used for everything, except the motherboard wifi adapter sits there on the same network doing nothing but being ready to accept a magic packet when the time comes? How would begin to go about this?**

Thanks in advance.